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The hardest part of evaluating any change is the bias of knowing which item is connected, getting someone else to do the changes is essential.Power cables are easy to double blind test. Get a helper to randomly switch them while you listen to the same recording for each test. Do it is such a way that you don't know which is which and the order is random using a number of trials. If you can reliably tell the difference use the one that you think sounds better. Most likely you will not be able to do any better than flipping a coin.
I would suggest finding cables which are thinner than either the manufacturers or the custom ones and see if any difference is consistantly heard between the three.
You would need to make a scoresheet with items graded from, say 1 to 5, and label them with attributes like - prescence. sound stage width, clarity etc.
A lot of listening and I am sure we would all like to see the results.
As said before: If you are happy that it improves the sound then that is all you need to do. In the long run it's your listening pleasure you are after!